The role of Rare Earth Elements (RE) in steel microstructure and heat treatment
Rare Earth Elements (RE) play a significant role in enhancing the properties of steel, particularly in terms of its microstructure and performance during heat treatment. These elements, which include lanthanum, cerium, neodymium, and others, contribute to the mechanical and physical properties of steel, making them valuable in various industrial applications.
1.Impact on Microstructure and Heat Treatment
Rare earth elements (RE) are highly reactive and play a significant role in refining the microstructure of steel. They readily combine with sulfur, oxygen, and hydrogen, making them effective desulfurizers and deoxidizers. This interaction helps eliminate the harmful effects of elements like arsenic, antimony, and bismuth, leading to a cleaner steel composition. Furthermore, REs can alter the morphology and distribution of inclusions in steel, which purifies the steel and improves its overall quality. It’s important to note that the solubility of REs in iron is quite low, typically not exceeding 0.5%. Except for lanthanum, all studied rare earth elements can form intermetallic compounds with iron.
2.Effects on Mechanical Properties
The addition of rare earth elements to steel enhances its plasticity and impact toughness, especially at low temperatures. REs also improve the creep resistance of heat-resistant steels, electric heating alloys, and high-temperature alloys. In some steel types, REs contribute to grain refinement and uniform microstructure, which in turn enhances the comprehensive mechanical properties of the steel.
3.Influence on Physical, Chemical, and Processing Properties
Rare earth elements significantly improve the oxidation resistance of steel. In 18-8 type stainless steels, REs enhance corrosion resistance, including resistance in concentrated nitric acid environments. Additionally, REs improve the fluidity of molten steel, leading to better casting yield and reduced thermal cracking in cast steel. They also significantly enhance the hot working properties of high-chromium stainless steel and improve the weldability of steel.
Applications of Rare Earth Elements in Steel
1.Usage in Various Steel Types
Rare earth elements are applied across a wide range of steel types, including low-alloy steels, alloy structural steels, bearing steels, tool steels, stainless and corrosion-resistant steels, electric heating alloys, and cast steels.
2.Importance of Controlled Addition
To consistently achieve the beneficial effects of rare earth elements on steel microstructure and properties, it is crucial to accurately control their content during the steelmaking process.
3.Future Development
China is rich in rare earth resources, and there is a significant opportunity to further explore and develop the mechanisms and applications of rare earth elements in steel. Enhancing our understanding and utilization of these elements can lead to further improvements in steel performance and quality.
Rare earth elements are vital in refining steel microstructure, improving mechanical properties, and enhancing the processing capabilities of various steel types. Their effective use in steelmaking holds great potential for advancing the quality and performance of steel products.